Deformed spin- <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mfrac><mml:mn>1</mml:mn><mml:mn>2</mml:mn></mml:mfrac></mml:math> square lattice in antiferromagnetic <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>NaZnVOPO</mml:mi><mml:mn>4</mml:mn></mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:msub><mml:mi>HPO</mml:mi><mml:mn>4</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mrow></mml:math>

نویسندگان

چکیده

We report the structural and magnetic properties of a new spin-$\frac12$ antiferromagnet NaZnVOPO$_4$(HPO$_4$) studied via x-ray diffraction, susceptibility, high-field magnetization, specific heat, $^{31}$P nuclear resonance (NMR) measurements, as well density-functional band-structure calculations. While thermodynamic this compound are described by $J_1-J_2$ square-lattice model, \textit{ab initio} calculations suggest significant deformation spin lattice. From fits to susceptibility we determine averaged nearest-neighbor second-neighbor exchange couplings $\bar J_1\simeq -1.3$ K J_2\simeq 5.6$ K, respectively. Experimental saturation field 15.3\,T is consistent with these estimates if 20\% spatial anisotropy in $J_1$ taken into account. Specific heat data signal onset long-range order at $T_{\rm N} \simeq 2.1$ which further supported sharp peak NMR spin-lattice relaxation rate. The spectra mark superposition two P lines due noneqivalent sites where broad line strong hyperfine coupling short $T_1$ identified P(1) site located within planes, while narrow weak long designated P(2) between planes.

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ژورنال

عنوان ژورنال: Physical review

سال: 2022

ISSN: ['0556-2813', '1538-4497', '1089-490X']

DOI: https://doi.org/10.1103/physrevb.106.024426